Hello Kirk,
Regarding your passwords syncing with your pc and iPhone you can use iCloud for Windows, you can click or tap here for more info.
Regarding multitasking, while listening to our podcast. If you download and use the Google Chrome web browser you will have this ability if you are playing the podcast directly from community.komando.com/listen
Alternatively, you can set up your favorite podcast player to download our podcasts, most podcast players will continue to play audio in the background while you use other apps on your iPhone.
Happy Listening!